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Acylation of electrophilic olefins through decatungstate-photocatalyzed activation of aldehydes

Articolo
Data di Pubblicazione:
2007
Abstract:
Ketones were prepared by the photocatalytic generation of acyl radicals from aldehydes and trapping them with equimolar amounts of electrophilic alkenes. Photocatalysis with tetrabutylammonium decatungstate is effective also at low temperatures (−20 to −50 °C), thus minimizing radical decarbonylation and allowing acylation by highly substituted aldehydes.
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
RADICALS; ACYLATION; PHOTOCATALYSIS
Elenco autori:
Albini, Angelo; Fagnoni, Maurizio; Dondi, Daniele; Esposti, Silvia
Autori di Ateneo:
DONDI DANIELE
FAGNONI MAURIZIO
Link alla scheda completa:
https://iris.unipv.it/handle/11571/35613
Pubblicato in:
ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Journal
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