The photochemistry of lomefloxacin. An aromatic carbene as the key intermediate in both photodecomposition and photocarcinogenesis
Articolo
Data di Pubblicazione:
1997
Abstract:
Irradiation of the 6,8-difluoroquinolone antibiotic lomefloxacin
causes selective heterolytic defluorination from
position 8 and leads to products rationalized as arising from
the cation either via nucleophile addition or intramolecular
carbene C–H insertion and hydrogen transfer.
causes selective heterolytic defluorination from
position 8 and leads to products rationalized as arising from
the cation either via nucleophile addition or intramolecular
carbene C–H insertion and hydrogen transfer.
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
photochemistry; lomefloxacin. carbene
Elenco autori:
Fasani, Elisa; Mella, Mariella; Caccia, D.; Tassi, S.; Fagnoni, Maurizio; Albini, Angelo
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