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Iridium-Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides

Articolo
Data di Pubblicazione:
2015
Abstract:
Iridium-catalyzed enantioselective allylic alkylation of branched racemic carbonates with functionalized alkylzinc bromide reagents is described. Enabled by a chiral Ir/(P,olefin) complex, the method described allows allylic substitution with various primary and secondary alkyl nucleophiles with excellent regio- and enantioselectivities. The developed reaction was showcased in a concise, asymmetric synthesis of (-)-preclamol.
Tipologia CRIS:
1.1 Articolo in rivista
Elenco autori:
Hamilton, Jy; Sarlah, D; Carreira, Em
Autori di Ateneo:
SARLAH DAVID
Link alla scheda completa:
https://iris.unipv.it/handle/11571/1412394
Pubblicato in:
ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Journal
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