An Investigation on Gel-State Electrolytes for Solar Cells Sensitized with β-Substituted Porphyrinic Dyes

The presence of a liquid electrolyte in dye-sensitized solar cells (DSSCs) is known to limit the time stability of these devices due to leakage and evaporation phenomena. To overcome this issue, gel-state electrolytes may represent a good solution in order to maintain stability and good performances, albeit at lower costs. In the present work, two different kinds of gel-electrolytes, based on poly (methyl methacrylate) (PMMA) and nanoclay agents, were investigated in DSSC-devices sensitized using β-substituted Zn-porphyrins (namely ZnPC4 and ZnPC12) with enveloping alkoxy chains of different lengths, able to produce a coverage of the photoanode surface. The highest power conversion efficiency (PCE) values equal to 1.06 ± 0.04% and 1.55 ± 0.26% were obtained for ZnPC12 (with longer alkoxy chains) with PMMA- and nanoclay-based electrolytes respectively. The properties of the photoanode/electrolyte interface as well as the influence of the gelling agents on the final properties of the obtained devices were thoroughly characterized.