Data di Pubblicazione:
1992
Abstract:
Arylsulfonamides act as efficient locking fragments in the Ni(II) template cyclization of open-chain tetramines, in the presence of formaldehyde, to give cyclam-like azamacrocycles. In particular, if ferrocenesulfonamide is used, a ferrocene-metallocyclam conjugate is obtained, which releases two electrons according to two distinct and consecutive one-electron steps (Fc/Fc+ and Ni(II)/Ni(III))
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
macrocyclic ligands; Ni(II); ferrocene; electrochemistry; template synthesis
Elenco autori:
De Blas, Andres; Desantis, Giancarlo; Fabbrizzi, Luigi; Licchelli, Maurizio; Mangano, CARLO PAOLO; Pallavicini, Piersandro
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