Quadrupolar projection of excluded-volume interactions in biaxial nematic liquid crystals
Academic Article
Publication Date:
2006
abstract:
We compute the quadrupolar approximation to the excluded-volume interaction between hard
spherocuboids, which applies to both platelets and spheroplatelets as special cases. We show that this approximation
can be written as the superposition of two London interactions: one attractive and the other repulsive.
This conclusion also proves why the phase diagram for the excluded-volume interaction of spherocuboids is
expected to feature a direct isotropic-to-biaxial transition at a single Landau point.
spherocuboids, which applies to both platelets and spheroplatelets as special cases. We show that this approximation
can be written as the superposition of two London interactions: one attractive and the other repulsive.
This conclusion also proves why the phase diagram for the excluded-volume interaction of spherocuboids is
expected to feature a direct isotropic-to-biaxial transition at a single Landau point.
Iris type:
1.1 Articolo in rivista
Keywords:
spherocuboids; excluded volume interactions; Minkowski sum
List of contributors:
Rosso, Riccardo; Virga, EPIFANIO GUIDO GIOVANNI
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