A simple and versatile Re-catalyzed Meyer-Schuster rearrangement of propargylic alcohols to α,β-unsaturated carbonyl compounds
Academic Article
Publication Date:
2009
abstract:
Insummary, using the readily available [ReOCl3(OPPh3)DMS)] complex we have developed a new general catalytic procedure for the rapid and efficient 1,3-rearrangement of free secondary alcohols to the corresponding alpha-beta usatured carbonyl compounds with virtually complete E stereoselectivity.
Iris type:
1.1 Articolo in rivista
Keywords:
Meyer-Schuster; propargylic alcohol; α; β-unsaturated carbonyl compounds
List of contributors:
Stefanoni, Massimo; Luparia, Marco; Porta, Alessio; Zanoni, Giuseppe; Vidari, Giovanni
Published in: