The photochemical approach to the functionalization of open-chain and cyclic alkanes: 2. Hydrogen abstraction
Academic Article
Publication Date:
1996
abstract:
Chloranil (Chl) has been irradiated in the presence of the alkanes 2,3-dimethylbutane, cyclohexane, norbornane, adamantane in acetonitrile. The primary step is hydrogen abstraction by triplet Chl, as confirmed by the detection of the ChlH radical. Hydrogen abstraction from the alkanes is unselective.
Iris type:
1.1 Articolo in rivista
Keywords:
PHOTOCHEMISTRY; Hydrogen abstraction
List of contributors:
Mella, Mariella; Freccero, Mauro; Albini, Angelo
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