Novel Pathways for Oxygen Insertion into Unactivated C-H Bonds by Dioxiranes. Transition Structures for Stepwise Routes via Radical Pairs and Comparison with the Concerted Pathway.
Articolo
Data di Pubblicazione:
2003
Abstract:
The oxygen insertion into C-H bonds (of methane, isobutane, and acetone) by dioxiranes (parent dioxirane and dimethyldioxirane) to give alcs. was studied with the DFT theory, using both restricted and unrestricted B3LYP methods
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
Oxygen Insertion; DIOXIRANES; reaction mechanism
Elenco autori:
Freccero, Mauro; Gandolfi, Remo; SARZI AMADE', M.; Rastelli, A.
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