Cationic and Radical Intermediates in the Acid Photorelease from Aryl Sulfonates and Phosphates
Articolo
Data di Pubblicazione:
2011
Abstract:
The irradiation of a series of phenyl sulfonates and phosphates leads to the quantitative release of
acidity with a reasonable quantum yield (ยช0.2). Products characterization, ion chromatography analysis
and potentiometric titration are consistent with the intervening of two different paths in this reaction,
viz. cationic with phosphates and (mainly) radical with sulfonates.
acidity with a reasonable quantum yield (ยช0.2). Products characterization, ion chromatography analysis
and potentiometric titration are consistent with the intervening of two different paths in this reaction,
viz. cationic with phosphates and (mainly) radical with sulfonates.
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
aryl sulphonates; aryl phosphates; photoacid generator; aryl cation; radical
Elenco autori:
Terpolilli, M; Merli, Daniele; Protti, Stefano; Dichiarante, V; Fagnoni, Maurizio; Albini, Angelo
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